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Abbreviations: ABTS: (2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)

10.1002/advs.202104194 Adv Sci (Weinh) 299 YuanR

& Pirrotta, V

The free energy profiles of the afatinib reaction in both EGFR and solution demonstrate a classic Michael addition in which the NA step is rate-limiting and a stable intermediate is formed before reprotonation to the thiol adduct state